中国知网的一篇文献,谁可以登陆的帮忙翻译一下,不多 有机化学期刊 1991 年第5期
题名:手性桃潜蛾性信息素的新合成路线
摘要
The enantiomeric 14-methyl-1-octadecenes were prepared by cross coupling reaction between the Grignard reagent of 12-Chloro-1-dodecene from 10-undecenoic acid and the enantiomeric 1-Bromo-2-methylhexane from corresponding (R) or (S) 2-methylhexanoic acidunder the catalysis of Li_2CuCl_4,The overall yield of the each enantiomer is about 30% fromthe racemic 2-methylhexanoic acid and the optical purity is approximately 100%.The (S)-enantiomer has showed strong bio-activity as the sex pheromone of peach leafminer moth in field tests.
题名:手性桃潜蛾性信息素的新合成路线
摘要
The enantiomeric 14-methyl-1-octadecenes were prepared by cross coupling reaction between the Grignard reagent of 12-Chloro-1-dodecene from 10-undecenoic acid and the enantiomeric 1-Bromo-2-methylhexane from corresponding (R) or (S) 2-methylhexanoic acidunder the catalysis of Li_2CuCl_4,The overall yield of the each enantiomer is about 30% fromthe racemic 2-methylhexanoic acid and the optical purity is approximately 100%.The (S)-enantiomer has showed strong bio-activity as the sex pheromone of peach leafminer moth in field tests.
